Systematic study of the substitution effect on the tetrel bond between 1,4-diazabicyclo[2.2.2]octane and TH3X-Reference-Cited by-同舟云学术

Systematic study of the substitution effect on the tetrel bond between 1,4-diazabicyclo[2.2.2]octane and TH3X

Published:2019 Issue:32 Volume:9 Page:18459-18466
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Hou Mingchang¹²³⁴⁵,Jin Kunyu¹²³⁴⁵,Li Qingzhong¹²³⁴⁵^ORCID,Liu Shufeng⁶⁷⁸⁹¹⁰^ORCID

Affiliation:

1. The Laboratory of Theoretical and Computational Chemistry

2. School of Chemistry and Chemical Engineering

3. Yantai University

4. Yantai 264005

5. People's Republic of China

6. Shandong Key Laboratory of Biochemical Analysis

7. College of Chemistry and Molecular Engineering

8. Qingdao University of Science and Technology

9. Qingdao 266042

10. PR China

Abstract

A tetrel bond was characterized in the complexes of 1,4-diazabicyclo[2.2.2]octane (DABCO) with TH₃X (T = C, Si, Ge; X= –Me, –H, –OH, –NH₂, –F, –Cl, –Br, –I, –CN, –NO₂).

Funder

National Natural Science Foundation of China

Qingdao University of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/RA/C9RA03351C

Reference75 articles.

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5. Tetrel bond of pseudohalide anions with XH3F (X = C, Si, Ge, and Sn) and its role in SN2 reaction

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