Phase evolution of Cu2ZnSnS4 (CZTS) nanoparticles from in situ formed binary sulphides under solvothermal conditions

Author:

Ahmad Rameez12,Saddiqi Naeem-ul-Hasan12,Wu Mingjian34ORCID,Prato Mirko5ORCID,Spiecker Erdmann34ORCID,Peukert Wolfgang12ORCID,Distaso Monica12ORCID

Affiliation:

1. Institute of Particle Technology, Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Cauerstraße 4, 91058 Erlangen, Germany

2. Interdisciplinary Center for Functional Particle Systems, Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Haberstraße 9a, 91058, Erlangen, Germany

3. Institute of Micro- and Nanostructure Research and Center for Nanoanalysis and Electron Microscopy (CENEM), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Cauerstraße 3, 91058 Erlangen, Germany

4. Interdisciplinary Center for Nanostructure Films (IZNF), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Cauerstraße 3, 91058 Erlangen, Germany

5. Materials Characterization Facility, Istituto Italiano di Tecnologia (IIT), Via Morego 30, 16163 Genoa, Italy

Abstract

Cu2ZnSnS4 (CZTS) nanocrystals form both by direct nucleation and growth and by conversion of binary sulphides into the quaternary phase via internal recrystallization processes.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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