Affiliation:
1. Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 South Cass Avenue, Lemont, IL 60439, USA
Abstract
The parasitic reaction between the cathode and the electrolyte is facilitated by the coordination bonding between the carboxyl groups and the interfacial transition metal ions. A stable cathode electrolyte interface can be achieved by (1) blocking coordination bond, (2) retarding electron transfer, and (3) hindering the diffusion of protons towards the cathode material.
Funder
U.S. Department of Energy
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis
Cited by
5 articles.
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