Regio- and diastereoselective transition metal-free hydroalkylation of <i>N</i>-allenyl sulfonamides by push–pull 2-alkynylquinolines-Reference-Cited by-同舟云学术

Regio- and diastereoselective transition metal-free hydroalkylation of N-allenyl sulfonamides by push–pull 2-alkynylquinolines

Published:2022 Issue:42 Volume:20 Page:8269-8272
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Dehghanpour Kalan Reza¹,Amiri Kamran¹^ORCID,Rominger Frank²,Balalaie Saeed¹^ORCID,Bijanzadeh Hamid Reza³

Affiliation:

1. Peptide Chemistry Research Institute, K. N. Toosi University of Technology, P. O. Box 15875-4416, Tehran, Iran

2. Organisch-Chemisches Institut der Universität Heidelberg, Im Neuenheimer Feld 271, D-69120 Heidelberg, Germany

3. Department of Environmental Sciences, Faculty of Natural Resources and Marine Sciences, Tarbiat Modares University, P.O. Box 46414-356, Noor, Iran

Abstract

Herein we describe a novel and efficient synthetic strategy to construct the linear homoallylic quinolone structures through the regio- and diastereoselective transition metal-free intramolecular addition of enolized 2-alkynylquinoline to allenamide.

Funder

Iran National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/OB/D2OB01362B

Reference25 articles.

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4. Transition Metal–Catalyzed Allylic C(sp 3 )–H Functionalization via η 3 ‐Allylmetal Intermediate

5. Metal-Catalyzed Intermolecular Hydrofunctionalization of Allenes: Easy Access to Allylic Structures via the Selective Formation of C–N, C–C, and C–O Bonds

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