Ambient access to a new family of pyrrole-fused pyrazine nitrones via 2-carbonyl-N-allenylpyrroles-Reference-Cited by-同舟云学术

Ambient access to a new family of pyrrole-fused pyrazine nitrones via 2-carbonyl-N-allenylpyrroles

Published:2020 Issue:24 Volume:7 Page:4019-4025
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Ivanov Andrey V.¹²³⁴^ORCID,Martynovskaya Svetlana V.¹²³⁴^ORCID,Shcherbakova Victoria S.¹²³⁴^ORCID,Ushakov Igor A.¹²³⁴,Borodina Tatyana N.¹²³⁴^ORCID,Bobkov Alexander S.⁵⁶⁷⁴^ORCID,Vitkovskaya Nadezhda M.⁵⁶⁷⁴^ORCID

Affiliation:

1. Favorsky Irkutsk Institute of Chemistry

2. Siberian Branch of the Russian Academy of Sciences

3. 664033 Irkutsk

4. Russian Federation

5. Laboratory of Quantum Chemical Modeling of Molecular Systems

6. Irkutsk State University

7. 664003 Irkutsk

Abstract

The chemo-, regio- and stereoselective synthesis of pyrrole-fused pyrazine nitrones via the direct reaction of 2-carbonyl-N-allenylpyrroles (readily accessible from the corresponding NH-pyrroles) with hydroxyl amine hydrochloride has been developed.

Funder

Ministry of Science and Higher Education of the Russian Federation

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/QO/D0QO00762E

Reference51 articles.

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4. Additions of Organometallic Reagents to CN Bonds: Reactivity and Selectivity

5. The Discovery of Novel Metal-Induced Reactions of Nitrones: Not Only Electrophiles and Reagents for [3+2] Cycloadditions

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