Hydrogen-free hydrogenation of nitrobenzene via direct coupling with cyclohexanol dehydrogenation over ordered mesoporous MgO/SBA-15 supported Cu nanoparticles-Reference-Cited by-同舟云学术

Hydrogen-free hydrogenation of nitrobenzene via direct coupling with cyclohexanol dehydrogenation over ordered mesoporous MgO/SBA-15 supported Cu nanoparticles

Published:2020 Issue:64 Volume:10 Page:38755-38766
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Marella Ravi Kumar¹²³⁴⁵^ORCID,Madduluri Venkata Rao⁶⁷⁸⁴,Lakkaboyana Sivarama Krishna⁹¹⁰¹¹,Hanafiah Marlia M.¹²¹³¹⁴¹⁵¹¹,Yaaratha Sarala¹⁶¹⁷¹⁸⁴

Affiliation:

1. Department of Chemistry (H & S)

2. PACE Institute of Technology & Sciences

3. Ongole 523001

4. India

5. Department of Chemical Engineering

6. Catalysis and Fine Chemicals Division

7. Indian Institute of Chemical Technology

8. Hyderabad 500007

9. School of Ocean Engineering

10. Universiti Malaysia Terengganu

11. Malaysia

12. Department of Earth Sciences and Environment

13. Faculty of Science and Technology

14. Universiti Kebangsaan Malaysia

15. 43600 UKM Bangi

16. Department of Chemistry

17. Chaitanya Bharathi Institute of Technology

18. Hyderabad 500 075

Abstract

Coupling of nitrobenzene and cyclohexanol over mesoporous Cu/MgO-SBA15 exhibited better conversion of 89% cyclohexanol, 82% nitrobenzene with remarkable yields of cyclohexanone (83%) and aniline (75%). The catalyst has stable activity up to 30 h.

Funder

University Grants Commission

Universiti Kebangsaan Malaysia

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/RA/D0RA06003H

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1. Heterogeneous Catalytic Hydrogenation Reactions in Continuous-Flow Reactors

2. Novelties of azobenzene synthesis via selective hydrogenation of nitrobenzene over nano-fibrous Ag-OMS-2 – Mechanism and kinetics