Diazaphosphinanes as hydride, hydrogen atom, proton or electron donors under transition-metal-free conditions: thermodynamics, kinetics, and synthetic applications-Reference-Cited by-同舟云学术

Diazaphosphinanes as hydride, hydrogen atom, proton or electron donors under transition-metal-free conditions: thermodynamics, kinetics, and synthetic applications

Published:2020 Issue:14 Volume:11 Page:3672-3679
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zhang Jingjing¹²³⁴⁵,Yang Jin-Dong¹²³⁴⁵^ORCID,Cheng Jin-Pei¹²³⁴⁵

Affiliation:

1. Center of Basic Molecular Science

2. Department of Chemistry

3. Tsinghua University

4. Beijing 100084

5. China

Abstract

A new 1,3,2-diazaphosphinane, serving as a formal hydride, hydrogen-atom or proton donor without transition-metal mediation was exploited thermodynamically and kinetically. And, its promising potentials in versatile syntheses have been demonstrated.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/C9SC05883D

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