Unlocking flavin photoacid catalysis through electrophotochemistry-Reference-Cited by-同舟云学术

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Unlocking flavin photoacid catalysis through electrophotochemistry

Published:2024 Issue:29 Volume:15 Page:11444-11454
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Gary Samuel¹,Woolley Jack²^ORCID,Goia Sofia³,Bloom Steven¹^ORCID

Affiliation:

1. Department of Medicinal Chemistry, University of Kansas, Lawrence, 66045, USA

2. Department of Physics, University of Warwick, Coventry, CV4 7AL, UK

3. Forensic Centre for Digital Scanning and 3D Printing, WMG, University of Warwick, Coventry, CV4 7AL, UK

Abstract

One untapped reactivity mode of flavins is excited-state proton transfer. We show that electrophotochemistry enables flavins to achieve this elusive reactivity, in addition to C–H functionalization protocols, expanding their mechanistic repertoire.

Funder

National Institute of General Medical Sciences

University of Kansas

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC03054K

Reference102 articles.

1. Synthetic applications of flavin photocatalysis: a review

2. Visible light flavin photo-oxidation of methylbenzenes, styrenes and phenylacetic acids

3. Halogenase-Inspired Oxidative Chlorination Using Flavin Photocatalysis

4. Reduction of Carbon−Carbon Double Bonds Using Organocatalytically Generated Diimide

5. Thiourea-Enhanced Flavin Photooxidation of Benzyl Alcohol

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