Synthesis and structural, magnetic and spectroscopic characterization of iron(<scp>iii</scp>) complexes with <i>in situ</i> formed ligands from methyl-2-pyridyl ketone transformations-Reference-Cited by-同舟云学术

Synthesis and structural, magnetic and spectroscopic characterization of iron(iii) complexes with in situ formed ligands from methyl-2-pyridyl ketone transformations

Published:2023 Issue:6 Volume:52 Page:1582-1594
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Tzani Sofia¹,Pissas Michael¹,Psycharis Vassilis¹^ORCID,Pantazis Dimitrios A.²^ORCID,Sanakis Yiannis¹,Raptopoulou Catherine P.¹^ORCID

Affiliation:

1. Institute of Nanoscience and Nanotechnology, NCSR “Demokritos”, 15310 Aghia Paraskevi, Athens, Greece

2. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, Germany

Abstract

New [FeIII3] and [FeIII4] complexes with ligands formed in situ from pyCOMe transformations contain both square pyramidal and octahedral metal sites, and display distinct Mössbauer hyperfine parameters.

Funder

Max-Planck-Gesellschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D2DT03944C

Reference54 articles.

1. Interesting copper(ii)-assisted transformations of 2-acetylpyridine and 2-benzoylpyridine

2. Families of Polynuclear Manganese, Cobalt, Nickel and Copper Complexes Stabilized by Various Forms of Di-2-pyridyl Ketone

3. Adventures in the Coordination Chemistry of Di‐2‐pyridyl Ketone and Related Ligands: From High‐Spin Molecules and Single‐Molecule Magnets to Coordination Polymers, and from Structural Aesthetics to an Exciting New Reactivity Chemistry of Coordinated Ligands

4. Indium(III) in the “Periodic Table” of Di(2-pyridyl) Ketone: An Unprecedented Transformation of the Ligand and Solid-State 115In NMR Spectroscopy as a Valuable Structural Tool

5. Stabilization of dimethyliron(II) and methylcobalt(I) complexes bearing a hemilabile 2-benzoylpyridine ligand in octahedral and square-pyramidal coordination

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