Regulating the magnetic dynamics of mononuclear β-diketone Dy(iii) single-molecule magnets through the substitution effect on capping N-donor coligands

Author:

Xi Jing12345,Ma Xiufang12345,Cen Peipei6745,Wu Yuewei12345,Zhang Yi-Quan8910115ORCID,Guo Yan12345,Yang Jinhui12345,Chen Lei12131415ORCID,Liu Xiangyu12345ORCID

Affiliation:

1. State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering

2. College of Chemistry and Chemical Engineering

3. Ningxia University

4. Yinchuan 750021

5. China

6. College of Public Health and Management

7. Ningxia Medical University

8. Jiangsu Key Laboratory for NSLSCS

9. School of Physical Science and Technology

10. Nanjing Normal University

11. Nanjing 210023

12. School of Environmental and Chemical Engineering

13. Jiangsu University of Science and Technology

14. Zhenjiang 212003

15. P. R. China

Abstract

Substituent change modulates the coordination symmetries and magnetic dynamics of five mononuclear β-diketonate-Dy(iii) complexes with capping N-donor coligands, which is studied by the combination of magnetic investigation and ab initio calculation.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Ningxia Province

Ningxia Medical University

State Key Laboratory of Coordination Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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