Multiple-decker and ring sandwich formation of manganese–benzene organometallic cluster anions: MnnBzn− (n = 1

Multiple-decker and ring sandwich formation of manganese–benzene organometallic cluster anions: MnnBzn− (n = 1–5 and 18)

Published:2016 Issue:37 Volume:18 Page:26049-26056
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Masubuchi Tsugunosuke¹²³⁴⁵,Iwasa Takeshi¹²³⁴⁵,Nakajima Atsushi¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Faculty of Science and Technology

3. Keio University

4. Yokohama 223-8522

5. Japan

Abstract

Organometallic multiple-decker sandwich clusters are topics of great interest due to their unique electronic and magnetic properties originating from anisotropic structures. A joint anion photoelectron spectroscopic and computational study reveals Mn_nBz_n⁻ (Bz = benzene) multiple-decker and ring sandwich formation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP05380G

Reference45 articles.

1. Will Spin-Relaxation Times in Molecular Magnets Permit Quantum Information Processing?

2. Quantum computing in molecular magnets

3. Signatures of Molecular Magnetism in Single-Molecule Transport Spectroscopy

4. Molecular spintronics using single-molecule magnets

5. Magnetic bistability in a metal-ion cluster

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