Hydrogen bond-directed supramolecular polymorphism leading to soft and hard molecular ordering

Author:

Aizawa Takumi12345,Aratsu Keisuke12345ORCID,Datta Sougata6375,Mashimo Takaki89105,Seki Tomohiro89105ORCID,Kajitani Takashi111213145,Silly Fabien1516171819ORCID,Yagai Shiki637520ORCID

Affiliation:

1. Division of Advanced Science and Engineering

2. Graduate School of Science and Engineering

3. Chiba University

4. Chiba 263-85223

5. Japan

6. Department of Applied Chemistry and Biotechnology, Graduate School of Engineering

7. Chiba 263-8522

8. Division of Applied Chemistry and Frontier Chemistry Center (FCC) Faculty of Engineering

9. Hokkaido University

10. Sapporo

11. Suzukakedai Materials Analysis Division

12. Technical Department

13. Tokyo Institute of Technology

14. Yokohama 226-8503

15. Université Paris-Saclay

16. CEA

17. CNRS

18. SPEC

19. TITANS

20. Institute for Global Prominent Research (IGPR)

Abstract

Transformation of metastable supramolecular stacks of hydrogen-bonded rosettes composed of an ester-containing barbiturated naphthalene into crystalline nanosheets occurs through the rearrangement of hydrogen-bonding patterns.

Funder

Japan Society for the Promotion of Science

Murata Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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