Low dimensional solids based on Mo6 cluster cyanides and Mn2+, Mn3+ or Cd2+ metal ions: crystal chemistry, magnetic and optical properties

Author:

Daigre Gilles12345,Lemoine Pierric12345ORCID,Pham Thi Diep12345,Demange Valérie12345ORCID,Gautier Régis12345ORCID,Naumov Nikolay G.67897ORCID,Ledneva Alexandra678,Amela-Cortes Maria12345,Dumait Noée12345,Audebrand Nathalie12345ORCID,Cordier Stéphane12345ORCID

Affiliation:

1. Univ Rennes

2. École Nationale Supérieure de Chimie de Rennes

3. CNRS

4. ISCR (Institut des Sciences Chimiques de Rennes) – UMR 6226

5. ScanMAT – UMS 2001

6. Nikolaev Institute of Inorganic Chemistry

7. 630090 Novosibirsk

8. Russia

9. Novosibirsk State University

Abstract

Five new cluster compounds based on [Mo6Bri8(CN)a6]2− and [Mo6Bri6Qi2(CN)a6]n− (Q = S, Se, n = 3, 4) cluster units have been synthesized and characterized.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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