Protonation of nitriles: isolation and characterization of alkyl- and arylnitrilium ions-Reference-Cited by-同舟云学术

Protonation of nitriles: isolation and characterization of alkyl- and arylnitrilium ions

Published:2016 Issue:20 Volume:45 Page:8494-8499
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Haiges Ralf¹²³⁴,Baxter Amanda F.¹²³⁴,Goetz Nadine R.⁵⁶⁷⁸,Axhausen Joachim A.⁵⁶⁷⁸,Soltner Theresa⁵⁶⁷⁸,Kornath Andreas⁵⁶⁷⁸,Christe Karl O.¹²³⁴

Affiliation:

1. Loker Hydrocarbon Research Institute and Department of Chemistry

2. University of Southern California

3. Los Angeles

4. USA

5. Department of Chemistry

6. Ludwig-Maximilians University Munich

7. 81377 Munich

8. Germany

Abstract

The reactions of acetonitrile, propionitrile, butyronitrile, N,N-dimethylaminoacetonitrile, benzonitrile, o-tolunitrile and 1,4-dicyanobenzene with HF/AsF₅ or HF/SbF₅ in anhydrous HF result in protonation of the nitrile.

Funder

Defense Threat Reduction Agency

National Science Foundation

Office of Naval Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT01301E

Reference45 articles.

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4. A New Reaction of Nitriles. I. Amides from Alkenes and Mononitriles1

5. Zur Kenntniss einer neuen Isochinolinsynthese

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