The robust, readily available cobalt(iii) trication [Co(NH2CHPhCHPhNH2)3]3+ is a progenitor of broadly applicable chirality and prochirality sensing agents

Author:

Luu Quang H.1234ORCID,Lewis Kyle G.1234,Banerjee Anik1234ORCID,Bhuvanesh Nattamai1234,Gladysz John A.1234ORCID

Affiliation:

1. Department of Chemistry

2. Texas A&M University

3. College Station

4. USA

Abstract

Salts of the title trication are the best chiral solvating agents found to date in terms of applicability to a broad spectrum of analytes, use at low loadings (avg 34 and 14 mol%, 2XBAr4 salts (X = Cl, I), and ability to analyze mixtures.

Funder

Welch Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference83 articles.

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2. G. G. Lyle and R. E.Lyle , in Asymmetric Synthesis , ed. J. D. Morrison , Academic Press, Inc. , New York, NY , 1983 , vol. 1 , ch. 2, pp. 13–27

3. V. Schurig , in Asymmetric Synthesis , ed. J. D. Morrison , Academic Press, Inc. , New York , 1983 , vol. 1 , ch. 5, pp. 59–60

4. Rapid determination of enantiomeric excess: a focus on optical approaches

5. Rapid Optical Methods for Enantiomeric Excess Analysis: From Enantioselective Indicator Displacement Assays to Exciton-Coupled Circular Dichroism

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