Chiral Brønsted acid-catalyzed intramolecular SN2′ reaction for enantioselective construction of a quaternary stereogenic center
Author:
Affiliation:
1. Department of Chemistry
2. Graduate School of Science
3. Tohoku University
4. Sendai 980-8578
5. Japan
6. Research and Analytical Center for Giant Molecules
Abstract
Construction of a quaternary stereogenic center was accomplished through the enantioselective intramolecular allylic substitution reaction of bis-trichloroacetimidate catalyzed by a chiral phosphoramide derivative.
Funder
Ministry of Education, Culture, Sports, Science and Technology
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC01942H
Reference101 articles.
1. Asymmetric Catalysis Special Feature Part I: Catalytic asymmetric synthesis of all-carbon quaternary stereocenters
2. J. Christoffers and A.Baro , Quaternary Stereocenters: Challenges and Solutions for Organic Synthesis , Wiley-VCH , Weinheim , 2005
3. Catalytic Enantioselective Construction of All-Carbon Quaternary Stereocenters
4. Metal-catalyzed asymmetric conjugate addition reaction: formation of quaternary stereocenters
5. Enantioselective synthesis of all-carbon quaternary stereogenic centers in acyclic systems
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