Selective mono- and dimetallation of a group 3 sandwich complex-Reference-Cited by-同舟云学术

Selective mono- and dimetallation of a group 3 sandwich complex

Published:2019 Issue:65 Volume:55 Page:9677-9680
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Martínez-Martínez Antonio J.¹²³^ORCID,Kennedy Alan R.⁴⁵⁶^ORCID,Paprocki Valerie⁷⁸⁹,Fantuzzi Felipe⁷⁸⁹^ORCID,Dewhurst Rian D.⁷⁸⁹^ORCID,O’Hara Charles T.⁴⁵⁶^ORCID,Braunschweig Holger⁷⁸⁹^ORCID,Mulvey Robert E.⁴⁵⁶^ORCID

Affiliation:

1. Supramolecular Organometallic Chemistry Laboratory CIQSO-Center for Research in Sustainable Chemistry & Department of Chemistry University of Huelva Campus El Camen

2. 21007 Huelva

3. Spain

4. WestCHEM

5. Department of Pure and Applied Chemistry University of Strathclyde Glasgow

6. UK

7. Institute for Inorganic Chemistry and Institute for Sustainable Chemistry & Catalysis with Boron Julius-Maximilians-Universität Würzburg Am Hubland

8. 97074 Würzburg

9. Germany

Abstract

While lithium alkyls and lithium amides do not metallate the scandium compound [(η⁵-C₅H₅)Sc(η⁸-C₈H₈)], a synergistic lithium–aluminium base-trap partnership cannot resist taking a bite with one C–H bond selectively cleaved from both Cp and COT rings.

Funder

Julius-Maximilians-Universität Würzburg

Engineering and Physical Sciences Research Council

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC03825F

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5. Selective Dimetalation of [Mn(η5-C5H5)(η6-C6H6)]: Crystal Structure and Conversion to Strained [n]Metalloarenophanes

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