Crystal structure of disordered nanocrystalline αII-quinacridone determined by electron diffraction

Author:

Gorelik T. E.123,Czech C.456,Hammer S. M.456,Schmidt M. U.456

Affiliation:

1. Institute of Physical Chemistry

2. University of Mainz

3. Mainz, Germany

4. Institute of Inorganic and Analytical Chemistry

5. Goethe-University Frankfurt am Main

6. Frankfurt am Main, Germany

Abstract

The nanocrystalline αII-phase of the industrially produced organic pigment quinacridone was studied by 3D electron diffraction. The average crystal structure was obtained directly from the data and validated by energy minimization. A model describing the experimentally observed diffuse scattering was proposed.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Reference46 articles.

1. W. Herbst and K.Hunger , Industrial Organic Pigments , Wiley-VCH , Weinheim , 3rd edn, 2004

2. Crystal structures of quinacridones

3. The bleaching of red coatings, which is frequently observed on aged cars, is not caused by a bleaching of the pigment, but by a decomposition of the coating (so-called chalking), resulting in a white, opaque layer which hides the red colour of the pigments

4. Quinacridone is internationally registered in the Colour Index as C.I. Pigment Violet 19. Trade names are e.g. ®Hostaperm Red Violet ER02 for the β-phase and ®Hostaperm Red E5B02 for the γ-phase (manufacturer: Clariant)

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