One-pot multiple reactions: asymmetric synthesis of 2,6-cis-disubstituted piperidine alkaloids from chiral aziridine
Author:
Affiliation:
1. Department of Chemistry
2. Hankuk University of Foreign Studies
3. Yongin
4. Korea
Abstract
2,6-cis-Disubstituted piperidine alkaloids were synthesized from chiral aziridines through one-pot multiple reactions.
Funder
National Research Foundation of Korea
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/OB/C6OB00806B
Reference54 articles.
1. Enantioselective Syntheses of 2-Alkyl- and 2,6-Dialkylpiperidine Alkaloids: Preparations of the Hydrochlorides of (−)-Coniine, (−)-Solenopsin A, and (−)-Dihydropinidine
2. Chiral non-racemic N-cyanomethyloxazolidines: the pivotal system of the CN(R,S) method
3. Nonracemic Betti Base as a New Chiral Auxiliary: Application to Total Syntheses of Enantiopure (2S,6R)-Dihydropinidine and (2S,6R)-Isosolenopsins
4. Stereocontrolled synthesis of piperidine alkaloids, (−)-241D and (−)-isosolenopsin
5. Synthesis of (−)-dihydropinidine, (2S,6R)-isosolenopsin and (+)-monomorine via a chiral synthon from l-aspartic acid
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