Theoretical and experimental study of peroxy and alkoxy radicals in the NO3-initiated oxidation of isoprene-Reference-Cited by-同舟云学术

Theoretical and experimental study of peroxy and alkoxy radicals in the NO3-initiated oxidation of isoprene

Published:2021 Issue:9 Volume:23 Page:5496-5515
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Vereecken L.¹²³^ORCID,Carlsson P. T. M.¹²³^ORCID,Novelli A.¹²³^ORCID,Bernard F.⁴⁵⁶,Brown S. S.⁷⁸⁹¹⁰⁸^ORCID,Cho C.¹²³^ORCID,Crowley J. N.¹¹¹²³^ORCID,Fuchs H.¹²³^ORCID,Mellouki W.⁴⁵⁶^ORCID,Reimer D.¹²³^ORCID,Shenolikar J.¹¹¹²³,Tillmann R.¹²³^ORCID,Zhou L.⁴⁵⁶,Kiendler-Scharr A.¹²³^ORCID,Wahner A.¹²³^ORCID

Affiliation:

1. Institute for Energy and Climate Research, Forschungszentrum Jülich GmbH

2. 52428 Jülich

3. Germany

4. Institut de Combustion, Aérothermique, Réactivité et Environnement (ICARE), CNRS (UPR 3021)/OSUC, 1C Avenue de la Recherche Scientifique

5. 45071 Orléans CEDEX 2

6. France

7. NOAA Chemical Sciences Laboratory

8. Boulder

9. USA

10. Department of Chemistry, University of Colorado Boulder

11. Atmospheric Chemistry Department, Max-Planck-Institut für Chemie

12. 55128 Mainz

Abstract

Under atmospheric conditions, nitrate-RO₂ radicals are equilibrated and react predominantly with HO₂, RO₂ and NO. The nitrate-RO chemistry is affected strongly by ring closure to epoxy radicals, impeding formation of MVK/MACR.

Funder

Horizon 2020 Framework Programme

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D0CP06267G

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