An unconventional route to an ambipolar azaheterocycle and its in situ generated radical anion-Reference-Cited by-同舟云学术

An unconventional route to an ambipolar azaheterocycle and its in situ generated radical anion

Published:2021 Issue:23 Volume:19 Page:5114-5120
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Das Sarasija¹²³⁴^ORCID,Choudhury Anwesha⁵⁶⁷⁴,Mandal Arnab¹²³⁴,Kumar Chandan¹²³⁴,Ranjan Sahoo Smruti⁸⁹¹⁰¹¹⁴,Bedi Anjan¹²¹³¹⁴⁴^ORCID,Shekhar Karmakar Himadri¹²³⁴,Gopal Ghosh Nani¹²³⁴,Dey Somnath¹⁵¹⁶¹⁷¹⁸^ORCID,Krishnan Iyer Parameswar⁵⁶⁷⁴^ORCID,Bhattacharyya Sayan¹²³⁴^ORCID,Zade Sanjio S.¹²³⁴^ORCID

Affiliation:

1. Department of Chemical Sciences

2. Indian Institute of Science Education and Research Kolkata

3. Mohanpur-741246

4. India

5. Department of Chemistry & Centre for Nanotechnology

6. Indian Institute of Technology Guwahati

7. Guwahati 781039

8. High Performance Computing Lab

9. Department of Physics

10. Indian Institute of Technology (ISM)

11. Dhanbad

12. Department of Chemistry

13. SRM Institute of Science and Technology

14. Chennai 603203

15. Institute of Crystallography

16. RWTH Aachen University

17. 52066 Aachen

18. Germany

Abstract

FeCl₃ mediated C–N coupling leads to an azaheterocycle, which undergoes one-electron reduction to form a fairly stable radical anion in situ. The azaheterocycle material showed balanced ambipolar charge transport in SCLC devices.

Funder

Science and Engineering Research Board

Indian Institute of Science Education and Research Kolkata

Department of Science and Technology, Ministry of Science and Technology, India

Council of Scientific and Industrial Research, India

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/OB/D1OB00826A