Spin-crossover cobalt(<scp>ii</scp>) complexes exhibiting temperature- and concentration-dependent optical changes in solution-Reference-Cited by-同舟云学术

Spin-crossover cobalt(ii) complexes exhibiting temperature- and concentration-dependent optical changes in solution

Published:2024 Issue:22 Volume:53 Page:9547-9553
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Izumiyama Naoki¹,Fujii Shun¹,Kato Kiichi²,Tokunaga Ryuya³,Hayami Shinya³⁴^ORCID,Nakaya Manabu¹²^ORCID

Affiliation:

1. Department of Material Science, Graduate School of Science, Josai University, 1-1 Keyakidai, Sakado, Saitama 350-0295, Japan

2. Department of Chemistry, Faculty of Science, Josai University, 1-1 Keyakidai, Sakado, Saitama 350-0295, Japan

3. Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan

4. Institute of Industrial Nanomaterials (IINa), Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan

Abstract

Terpyridine-based cobalt(ii) complexes with dynamic amine substituents have been found to exhibit not only solid-state spin-crossover behavior but also spectral changes associated with spin-state change in various organic solvents.

Funder

Japan Society for the Promotion of Science

Iketani Science and Technology Foundation

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00433G

Reference41 articles.

1. Spin crossover phenomena in Fe(ii) complexes

2. Thermal, pressure and light switchable spin-crossover materials

3. Switching of Molecular Spin States in Inorganic Complexes by Temperature, Pressure, Magnetic Field and Light: Towards Molecular Devices

4. Spin crossover with thermal hysteresis: practicalities and lessons learnt

5. Spin-Transition Polymers: From Molecular Materials Toward Memory Devices