A high-efficiency (12.5%) kesterite solar cell realized by crystallization growth kinetics control over aqueous solution based Cu2ZnSn(S,Se)4

Author:

Yin Kang12,Xu Xiao12,Wang Muyu12,Zhou Jiazheng12,Duan Biwen12,Shi Jiangjian1,Li Dongmei123,Wu Huijue1,Luo Yanhong123,Meng Qingbo143ORCID

Affiliation:

1. Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, P. R. China

2. School of Physical Sciences, University of Chinese Academy of Sciences, Beijing 100049, P. R. China

3. Songshan Lake Materials Laboratory, Dongguan 523808, P. R. China

4. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Abstract

By revealing a new crystallization mechanism of CZTSSe, a two-step selenization strategy is developed to obtain high-quality CZTSSe films, achieving the highest efficiency of 12.5% for aqueous-based CZTSSe solar cells.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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