An intramolecular ortho-assisted activation of the silicon–hydrogen bond in arylsilanes: an experimental and theoretical study

Author:

Durka Krzysztof12345ORCID,Urban Mateusz12345,Czub Maja12345,Dąbrowski Marek12345,Tomaszewski Patryk12345,Luliński Sergiusz12345ORCID

Affiliation:

1. Department of Physical Chemistry

2. Faculty of Chemistry

3. Warsaw University of Technology

4. 00-664 Warszawa

5. Poland

Abstract

An intramolecular activation of the Si–H bond in arylsilanes by selected ortho-assisting functional groups based on boron, carbon and phosphorus was investigated experimentally and by means of theoretical calculations.

Funder

Politechnika Warszawska

Fundacja na rzecz Nauki Polskiej

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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