Thermodynamics of inclusion within cyclodextrins and structural evidence of Cu(indomethacin)2 and Zn(indomethacin)2 complexes in aqueous solutions

Author:

Hipólito-Nájera Adrián Ricardo12345ORCID,Rodríguez-Laguna Norma12345,Reyes-García Luis I.12345,Gómez-Vidales Virginia64789,Rojas-Hernández Alberto1011121314ORCID,Gómez-Balderas Rodolfo12345ORCID,Moya-Hernández Rosario12345

Affiliation:

1. Laboratorio de Fisicoquímica Analítica

2. Unidad de Investigación Multidisciplinaria

3. Facultad de Estudios Superiores Cuautitlán

4. Universidad Nacional Autónoma de México

5. Cuautitlán Izcalli

6. Instituto de Química

7. Circuito exterior

8. Ciudad Universitaria

9. 04510 Coyoacán

10. Departamento de Química

11. Área de Química Analítica

12. UAM-Iztapalapa

13. 09340 Iztapalapa

14. Mexico

Abstract

Cu(IMC)2 and Zn(IMC)2 inclusion within cyclodextrins is spontaneous, the former driven by entropic and the last by enthalpic contributions.

Funder

Dirección General de Asuntos del Personal Académico, Universidad Nacional Autónoma de México

Consejo Nacional de Ciencia y Tecnología

Universidad Nacional Autónoma de México

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference40 articles.

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2. M. Valentovic , xPharm: The Comprehensive Pharmacology Reference , Elsevier , 2007 , pp. 1–5

3. Syntheses and Characterization of Anti-inflammatory Dinuclear and Mononuclear Zinc Indomethacin Complexes. Crystal Structures of [Zn2(Indomethacin)4(L)2] (L = N,N-Dimethylacetamide, Pyridine, 1-Methyl-2-pyrrolidinone) and [Zn(Indomethacin)2(L1)2] (L1 = Ethanol, Methanol)

4. C. T. Dillon , T. W.Hambley , B. J.Kennedy , P. A.Lay , J. E.Weder and Q.Zhou , in Metal ions in biological systems , ed. A. Sigel and H. Sigel , Marcel Dekker, Inc ., New York , 2004 , vol. 41

5. Interaction between indomethacin and heavy metal ions in aqueous solution

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