Electrolyte design implications of ion-pairing in low-temperature Li metal batteries-Reference-Cited by-同舟云学术

Electrolyte design implications of ion-pairing in low-temperature Li metal batteries

Published:2022 Issue:4 Volume:15 Page:1647-1658
ISSN:1754-5692
Container-title:Energy & Environmental Science
language:en
Short-container-title:Energy Environ. Sci.

Author:

Holoubek John¹^ORCID,Kim Kangwoon²,Yin Yijie²,Wu Zhaohui³,Liu Haodong¹,Li Mingqian³,Chen Amanda³^ORCID,Gao Hongpeng²,Cai Guorui¹,Pascal Tod A.¹²³⁴^ORCID,Liu Ping¹²³⁴^ORCID,Chen Zheng¹²³⁴^ORCID

Affiliation:

1. Department of NanoEngineering, University of California, San Diego, La Jolla, CA 92093, USA

2. Program of Materials Science and Engineering, University of California, San Diego, La Jolla, CA 92093, USA

3. Program of Chemical Engineering, University of California, San Diego, La Jolla, CA 92093, USA

4. Sustainable Power and Energy Center, University of California, San Diego, La Jolla, CA 92093, USA

Abstract

The reversibility of Li metal batteries suffers beneath 0 °C due to a heightened charge-transfer barrier. Herein, the introduction of ion-pairs within the electrolyte is shown to improve this behavior, enabling hundreds of cycles down to −40 °C.

Funder

National Science Foundation

National Aeronautics and Space Administration

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/EE/D1EE03422G

Reference49 articles.

1. Designing Advanced Lithium‐Based Batteries for Low‐Temperature Conditions

2. The low temperature performance of Li-ion batteries