Spin-forbidden near-infrared luminescence from a F3+ colour centre generated upon annealing in mechanochemically prepared nanocrystalline BaLiF3

Author:

Chowdhury Nishita1ORCID,Hutchison Wayne1ORCID,Riesen Nicolas2ORCID,Krausz Elmars3ORCID,Riesen Hans1ORCID

Affiliation:

1. School of Science, The University of New South Wales, ACT 2600, Australia

2. ARC IDEAL Research Hub, Future Industries Institute, STEM, University of South Australia, Adelaide, SA 5095, Australia

3. Research School of Chemistry, Australian National University, ACT 0200, Australia

Abstract

Annealing of mechanochemically prepared nanocrystalline BaLiF3 yields F3+ colour centres that exhibit unique singlet (excited state) to triplet (ground state) luminescence in the NIR.

Funder

University of New South Wales

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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