Structure–performance relationships of Cr/Ti/SiO2 catalysts modified with TEAl for oligomerisation of ethylene: tuning the selectivity towards 1-hexene-Reference-Cited by-同舟云学术

Structure–performance relationships of Cr/Ti/SiO2 catalysts modified with TEAl for oligomerisation of ethylene: tuning the selectivity towards 1-hexene

Published:2016 Issue:3 Volume:6 Page:731-743
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Cicmil D.¹²³⁴⁵,van Ravenhorst I. K.¹²³⁴⁵,Meeuwissen J.⁶⁷⁸,Vantomme A.⁶⁷⁸,Weckhuysen B. M.¹²³⁴⁵

Affiliation:

1. Inorganic Chemistry and Catalysis

2. Debye Institute for Nanomaterials Science

3. Utrecht University

4. 3584 CG Utrecht

5. The Netherlands

6. Total Research and Technology Feluy

7. B-7181 Seneffe

8. Belgium

Abstract

Ethylene oligomerisation properties of TEAl-modified Cr/Ti/SiO₂ ethylene polymerisation Phillips-type catalysts studied with in situ UV-vis-NIR diffuse reflectance spectroscopy, mass spectrometry and gas chromatography.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CY/C5CY01512J

Reference53 articles.

1. The Structure of Active Centers and the Ethylene Polymerization Mechanism on the Cr/SiO2 Catalyst: A Frontier for the Characterization Methods

2. Olefin polymerization over supported chromium oxide catalysts

3. Phillips Cr/Silica Catalyst for Ethylene Polymerization

4. An XPS study of the Phillips Cr/silica polymerization catalyst

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