Two binuclear Ni-inserted polyoxotantalates based on {NiTa<sub>10</sub>O<sub>32</sub>} units with catalytic activity-Reference-Cited by-同舟云学术

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Two binuclear Ni-inserted polyoxotantalates based on {NiTa₁₀O₃₂} units with catalytic activity

Published:2024 Issue:12 Volume:53 Page:5562-5566
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zhao Hui¹,Chen Hanhan¹,yang Zhang Ming¹,Yang Yuanyuan¹,Yang Zongfei¹^ORCID,Ma Pengtao¹^ORCID,Niu Jingyang¹^ORCID,Wang Jingping¹^ORCID

Affiliation:

1. Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Molecular Sciences, Henan University, Kaifeng, Henan 475004, China

Abstract

Two cases of hetero-polyoxotantalates containing {NiTa10} are reported for the first time. Ni as a heteroatom is located in the center of the {Ta10} unit. And 2 exhibits excellent catalytic performance in transesterification reactions.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00048J

Reference40 articles.

1. dl-Serine covalently modified multinuclear lanthanide-implanted arsenotungstates with fast photochromism

2. Green Oxidation of Isochromans to Isochromanones with Molecular Oxygen Catalyzed by a Tetranuclear Vanadium Cluster

3. Making one V^IV substitution for Mo on classical [MoV2O₄]²⁺ group: the first heterobimetallic Mo–V subunit in polyoxomolybdate–bisphosphonate family

4. Regulating Spin-State Switching by Integrating Polyoxometalate Anion into Spin Crossover System

5. Synthesis, structures and stability of three V-substituted polyoxoniobate clusters based on [TeNb9O33]17− units

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