Low-valent iron: an Fe(i) ate compound as a building block for a linear trinuclear Fe cluster-Reference-Cited by-同舟云学术

Low-valent iron: an Fe(i) ate compound as a building block for a linear trinuclear Fe cluster

Published:2015 Issue:73 Volume:51 Page:13890-13893
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Lichtenberg C.¹²³,Viciu L.¹²³,Vogt M.¹²³,Rodríguez-Lugo R. E.¹²³,Adelhardt M.⁴⁵⁶⁷⁸,Sutter J.⁴⁵⁶⁷⁸,Khusniyarov M. M.⁴⁵⁶⁷⁸,Meyer K.⁴⁵⁶⁷⁸,de Bruin B.⁹¹⁰¹¹¹²,Bill E.¹³¹⁴⁸,Grützmacher H.¹²³¹⁵¹⁶

Affiliation:

1. Department of Chemistry and Applied Biosciences

2. ETH Zürich

3. Switzerland

4. Department of Chemistry & Pharmacy

5. Friedrich-Alexander University

6. Erlangen - Nuremberg (FAU)

7. D-91058 Erlangen

8. Germany

9. Universiteit van Amsterdam

10. Faculty of Science

11. 1090 GS Amsterdam

12. The Netherlands

13. MPI für Chemische Energiekonversion

14. D-45470 Mülheim an der Ruhr

15. Lehn Institute of Functional Materials (LIFM)

16. Sun Yat-Sen University

Abstract

A low-valent, linear, trinuclear iron cluster was synthesized from a new Fe(i) ate compound with a redox-active diazadiene-diolefin ligand and fully characterized.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC04908C

Reference31 articles.

1. [(HL)2Fe6(NCMe)m]n+(m= 0, 2, 4, 6;n= −1, 0, 1, 2, 3, 4, 6): An Electron-Transfer Series Featuring Octahedral Fe6Clusters Supported by a Hexaamide Ligand Platform

2. Synthesis and Redox Properties of Triiron Complexes Featuring Strong Fe-Fe Interactions

3. Oxidative Group Transfer to a Triiron Complex to Form a Nucleophilic μ3-Nitride, [Fe3(μ3-N)]−

4. Multi-Site Reactivity: Reduction of Six Equivalents of Nitrite To Give an Fe6(NO)6 Cluster with a Dramatically Expanded Octahedral Core

5. Modulation of magnetic behavior vialigand-field effects in the trigonal clusters (PhL)Fe3L*3(L*= thf, py, PMe2Ph)

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