Halo-substituted benzenesulfonyls and benzenesulfinates: convenient sources of arenes in metal-catalyzed C–C bond formation reactions for the straightforward access to halo-substituted arenes

Author:

Li Haoran12345ORCID,Sasmal Arpan12345,Shi Xinzhe12345,Soulé Jean-François12345ORCID,Doucet Henri12345ORCID

Affiliation:

1. Univ Rennes

2. Ecole Nationale Supérieure de Chimie de Rennes

3. CNRS

4. ISCR-UMR 6226

5. F-35000 Rennes

Abstract

The use of halo-substituted ArSO2R as an aryl source in metal-catalyzed C–C bond formation reactions presents several advantages, as the reaction often proceeds without cleavage of the C–halo bonds.

Funder

China Scholarship Council

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference135 articles.

1. L. Ackermann , Modern arylation methods , Wiley , 2009

2. J. J. Li and G. W.Gribble , Palladium in Heterocyclic Chemistry , Pergamon , Amsterdam , 2000

3. E.-I. Negishi , Handbook of Organopalladium Chemistry for Organic Synthesis , Wiley , New York , 2002

4. Intermolecular Dehydrogenative Heck Reactions

5. Science of Synthesis: Cross Coupling and Heck-Type Reactions , ed. G. A. Molander , J. P. Wolfe and M. Larhed , Georg Thieme Verlag , Stuttgart, New York , 2013 , vol. 1–3

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