A new Mo(iv) complex with the pentadentate (N3O2) Schiff-base ligand: the first non-cyanide pentagonal–bipyramidal paramagnetic 4d complex-Reference-Cited by-同舟云学术

A new Mo(iv) complex with the pentadentate (N3O2) Schiff-base ligand: the first non-cyanide pentagonal–bipyramidal paramagnetic 4d complex

Published:2017 Issue:41 Volume:46 Page:14083-14087
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Mironov V. S.¹²³,Bazhenova T. A.⁴⁵⁶³,Manakin Yu. V.⁴⁵⁶³^ORCID,Lyssenko K. A.⁷⁸²³,Talantsev A. D.⁴⁵⁶³,Yagubskii E. B.⁴⁵⁶³

Affiliation:

1. Shubnikov Institute of Crystallography of Federal Scientific Research Centre “Crystallography and Photonics” RAS

2. Moscow

3. Russia

4. Institute of Problems of Chemical Physics

5. IPCP RAS

6. Chernogolovka

7. A. N. Nesmeyanov Institute of Organoelement Compounds

8. RAS

Abstract

Characterized both structurally and magnetically, a new molybdenum(iv) Schiff-base complex represents a novel family of the pentagonal–bipyramidal 4d-metal-based building blocks for construction of advanced single-molecule magnets.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT02912H

Reference46 articles.

1. Magnetic anisotropy in two- to eight-coordinated transition–metal complexes: Recent developments in molecular magnetism

2. 3d single-ion magnets

3. What is not required to make a single molecule magnet

4. A Criterion for the Anisotropy Barrier in Single-Molecule Magnets

5. Magnetic blocking in a linear iron(I) complex

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