Enantioselective synthesis of chiral porphyrin macrocyclic hosts and kinetic enantiorecognition of viologen guests
Author:
Affiliation:
1. Institute for Molecules and Materials
2. Radboud University
3. 6525 AJ Nijmegen
4. The Netherlands
5. Aix Marseille Univ
6. CNRS
7. Centrale Marseille
8. iSm2
9. Marseille
Abstract
Chiral guests display kinetic stereoselective threading through chiral porphyrin cages if their chirality is located at the chain ends and not in the centers, supporting the previously reported entron effect of threading.
Funder
European Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC05233G
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5. Facile synthesis and optical resolution of inherently chiral fluorescent calix[4]crowns: enantioselective recognition towards chiral leucinol
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