Electronic structures and spectroscopic signatures of diiron intermediates generated by O2 activation of nonheme iron(ii)–thiolate complexes-Reference-Cited by-同舟云学术

Electronic structures and spectroscopic signatures of diiron intermediates generated by O2 activation of nonheme iron(ii)–thiolate complexes

Published:2021 Issue:40 Volume:50 Page:14432-14443
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ekanayake Danushka M.¹,Pham Dao²,Probst Andrew L.²,Miller Joshua R.³,Popescu Codrina V.²^ORCID,Fiedler Adam T.¹^ORCID

Affiliation:

1. Department of Chemistry, Marquette University, Milwaukee, Wisconsin 53233, USA

2. Department of Chemistry, The College of Arts and Sciences, University of St. Thomas, St. Paul, Minnesota 55105, USA

3. Department of Chemistry, University of Wisconsin – Madison, Madison, Wisconsin 53706, USA

Abstract

Spectroscopic and computational methods are employed to elucidate the geometric and electronic structures of diiron intermediates arising from the reaction of biomimetic nonheme iron–thiolate complexes with O2.

Funder

National Institute of General Medical Sciences

University of St. Thomas

Division of Computer and Network Systems

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT02286E

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5. Structures of the Superoxide Reductase from Pyrococcus furiosus in the Oxidized and Reduced States ,

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