Organocatalyzed ring-opening polymerization (ROP) of functional β-lactones: new insights into the ROP mechanism and poly(hydroxyalkanoate)s (PHAs) macromolecular structure-Reference-Cited by-同舟云学术

Organocatalyzed ring-opening polymerization (ROP) of functional β-lactones: new insights into the ROP mechanism and poly(hydroxyalkanoate)s (PHAs) macromolecular structure

Published:2020 Issue:15 Volume:11 Page:2640-2652
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Shakaroun Rama M.¹²³⁴⁵^ORCID,Jéhan Philippe⁶⁷⁸⁵,Alaaeddine Ali⁹¹⁰¹¹¹²¹³,Carpentier Jean-François¹²³⁴⁵^ORCID,Guillaume Sophie M.¹²³⁴⁵^ORCID

Affiliation:

1. Univ. Rennes

2. CNRS

3. Institut des Sciences Chimiques de Rennes

4. F-35042 Rennes

5. France

6. Centre Régional de Mesures Physiques de l'Ouest-CRMPO

7. ScanMAT UMS 2001

8. Université de Rennes 1

9. Univ. Libanaise

10. Campus Universitaire Rafic Hariri Hadath

11. Faculté des Sciences

12. Laboratoire de Chimie Médicinale et des Produits Naturels

13. Beirut

Abstract

The organocatalyzed ROP of some 4-alkoxymethylene-β-propiolactones (BPL^ORs) towards the formation of the corresponding poly(hydroxyalkanoate)s (PHAs; PBPL^ORs) is investigated simply using basic organocatalysts of the guanidine (TBD), amidine (DBU) or phosphazene (BEMP) type.

Funder

Université Libanaise

Université de Rennes 1

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2020/PY/D0PY00125B

Reference76 articles.

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