NMR probe effects on trans-philicity and trans-influence ladders in square planar Pt(ii) complexes

Author:

Tsipis Athanassios C.1234ORCID

Affiliation:

1. Department of Chemistry

2. University of Ioannina

3. Ioannina 45110

4. Greece

Abstract

trans-Philicity ladders for trans-Pt(PMe3)2(X)L (X = H, CH3, CO, NH2, OH2, Cl) complexes are built by σiso X NMR descriptors. Correlations of the σiso X vs popular electronic/structural parameters of L and X demonstrate the origin of trans philicity.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference47 articles.

1. R. G. Wilkins , The study of kinetics and mechanism of reactions of transition metal complexes , Allyn and Bacon , Boston , 1974 , p. 229

2. J. E. Huheey , Inorganic Chemistry , Harper and Row , New York , 2nd edn, 1978 , pp. 498–503

3. M. L. Tobe , Inorganic Reaction Mechanisms , Nelson , Southampton, Great Britain , 1972 , vol. 191, pp. 58–88

4. Cis labilization of ligand dissociation. I. Carbon-13 monoxide exchange and phosphorus ligand substitution with bromopentacarbonylmanganese and bromopentacarbonylrhenium

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