Crystal structure, magneto-structural correlation, thermal and electrical studies of an imidazolium halometallate molten salt: (trimim)[FeCl4]

Author:

González-Izquierdo Palmerina12345,Fabelo Oscar67ORCID,Beobide Garikoitz8910115ORCID,Cano Israel12131415ORCID,Ruiz de Larramendi Idoia8910115ORCID,Vallcorba Oriol16175ORCID,Fernández Jesús Rodríguez12345,Fernández-Díaz María Teresa67,de Pedro Imanol12345ORCID

Affiliation:

1. CITIMAC

2. Facultad de Ciencias

3. Universidad de Cantabria

4. 39005 Santander

5. Spain

6. Institut Laue-Langevin

7. France

8. Departamento de Química Inorgánica

9. Facultad de Ciencia y Tecnología

10. Universidad del País Vasco

11. Bilbao

12. School of Chemistry

13. University of Nottingham

14. Nottingham

15. UK

16. ALBA Synchrotron Light Source

17. Barcelona

Abstract

We present a novel halometallate molten salt based on imidazolium cation with two structural transitions from 100 to 400 K which has been studied by X-ray and neutron diffraction techniques. Furthermore, the magnetic structure at low temperature and the ionic conductivity is also described.

Funder

Universidad de Cantabria

Euskal Herriko Unibertsitatea

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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