Enhanced photoreduction of water catalyzed by a cucurbit[8]uril-secured platinum dimer-Reference-Cited by-同舟云学术

Enhanced photoreduction of water catalyzed by a cucurbit[8]uril-secured platinum dimer

Published:2021 Issue:46 Volume:12 Page:15347-15352
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Rabbani Ramin¹^ORCID,Saeedi Sima¹,Nazimuddin Md¹,Barbero Héctor¹²,Kyritsakas Nathalie³,White Travis A.¹,Masson Eric¹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, Ohio University, Athens, Ohio 45701, USA

2. GIR MIOMeT, IU CINQUIMA/Química Inorgánica, Facultad de Ciencias, Universidad de Valladolid, Valladolid, E47011, Spain

3. Molecular Tectonics Laboratory, University of Strasbourg, UMR UDS-CNRS 7140, Institut le Bel, F-67000 Strasbourg, France

Abstract

The cucurbit[8]uril macrocycle can secure a platinum terpyridyl complex into a particularly reactive dimer that catalyzes the photoreduction of water.

Funder

Fundación Alfonso Martín Escudero

American Chemical Society Petroleum Research Fund

Division of Chemistry

Ohio University

Université de Strasbourg

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC03743A

Reference62 articles.

1. Evidence for Pt(II)-Based Molecular Catalysis in the Thermal Reduction of Water into Molecular Hydrogen

2. Photochemical H2 Evolution Catalyzed by Porphyrin-based Cubic Cages Singly and Doubly Encapsulating PtCl2(4,4′-dimethyl-2,2′-bipyridine)

3. Photo-hydrogen-evolving activity of chloro(terpyridine)platinum(ii): a single-component molecular photocatalyst

4. Frontier orbital engineering of photo-hydrogen-evolving molecular devices: a clear relationship between the H2-evolving activity and the energy level of the LUMO

5. Synthesis, crystal structure, spectroscopic and electrochemical properties, and H2-evolving activity of a new [PtCl(terpyridine)]+ derivative with viologen-like redox properties

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