Timing matters: pre-assembly <i>versus</i> post-assembly functionalization of a polyoxovanadate

Timing matters: pre-assembly versus post-assembly functionalization of a polyoxovanadate–organic cuboid

Published:2022 Issue:19 Volume:13 Page:5718-5725
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Guo Ji¹,Liu Junrui²,Cui Yingcui¹,Liu Chuanhong¹,Wang Yangming¹,Wang Mou¹,Huang Danmeng¹,Chen Guanying¹^ORCID,Wang Wei²^ORCID,Xia Debin¹^ORCID,Fang Xikui¹^ORCID

Affiliation:

1. MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China

2. CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Xiamen, Fujian, 361021, China

Abstract

Introducing functional groups at different stages in the assembly of a metal–organic cage has led to two distinct, endo-functionalized products, a result attributed to kinetic trapping in a process generally operating under thermodynamic control.

Funder

Central University Basic Research Fund of China

National Natural Science Foundation of China

Natural Science Funds for Distinguished Young Scholars of Heilongjiang Province

Youth Innovation Promotion Association of the Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC00533F

Reference40 articles.