Steric hindrance driven passivating cations for stable perovskite solar cells with an efficiency over 24%

Author:

Rakstys Kasparas1,Xia Jianxing2,Zhang Yi2,Siksnelyte Kotryna1,Slonopas Andre3,Dyson Paul J.2ORCID,Getautis Vytautas1ORCID,Nazeeruddin Mohammad Khaja2ORCID

Affiliation:

1. Department of Organic Chemistry, Kaunas University of Technology, Radvilenu pl. 19, Kaunas 50254, Lithuania

2. Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne, CH-1951 Sion, Switzerland

3. Johns Hopkins University, Whiting School of Engineering, Department of Materials Science and Engineering, USA

Abstract

Surficial passivated PSCs with power conversion efficiency over 24% have been achieved based on perfluorinated cation PFPDMAI2 having sterically hindered ortho-methylammonium iodide functional units with a long-term operational stability over 1500 h.

Funder

Lietuvos Mokslo Taryba

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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