Formation of cisoid-η4(5e)-butadienylrhenium complexes by coupling of alkene and alkyne ligands
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
Molecular Medicine
Link
http://pubs.rsc.org/en/content/articlepdf/1995/C3/C39950000767
Reference12 articles.
1. Reactions of co-ordinated ligands. Part 29. The formation of a 1,3-diene at a molybdenum centre by linking of but-2-yne with an alkene; X-ray crystal structures of [Mo(η2-o-Ph2PC6H4CHCH2)(η2-MeC2Me)(η-C5H5)][BF4] and [Mo(NCMe)(η4-o-MeCHCMe–CHCHC6H4PPh2)(η-C5H5)][BF4]
2. Alkyne/alkene coupling reactions leading to 1,3-diene and 2,4-pentadienyl complexes of rhenium(III). Activation of dichloro(.eta.5-pentamethylcyclopentadienyl)(.eta.2-alkyne)rhenium(III) by Broensted acid catalysis
3. Patterns of Stoichiometric and Catalytic Reactions of Organozirconium and Related Complexes of Synthetic Interest
4. Reaction of cationic cyclobutadineruthenium complexes with hydride anion donors; evidence for the formation of η4(5e) butadienyl species and fragmentation of the cyclobutadiene ring: crystal structure of [RuC(Ph)–η3-{C(Ph)·CH(Ph)·CH(Ph)}-(η-C5H5)] and [Ru2(µ-CO){µ-(Z)-C(Ph)CH(Ph)}(CO)2(η4-C4Ph4)(η-C5H5)]
Cited by 7 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Facile Migratory Insertion of a N-Heterocyclic Carbene into a Ruthenium−Carbon Double Bond: A New Type of Reaction of a NHC Ligand;Journal of the American Chemical Society;2006-04-29
2. Reaction Chemistry of the Carbenoid Butadienyl Complex Ion [CpCo(σ,η 4 ‐C 4 HMe 4 )] + Formed by Protonation of the Cyclobutadiene Complex [CpCo(C 4 Me 4 )];European Journal of Inorganic Chemistry;2005-03
3. Selective CC Bond Formation between Alkynes Mediated by the [RuCp(PR3)]+ Fragment Leading to Allyl, Butadienyl, and Allenyl Carbene Complexes—An Experimental and Theoretical Study;Chemistry - A European Journal;2002-09-02
4. The reaction of ferrocenyl acetylene with [RuCp(PR3)(CH3CN)2]PF6 (R=Me, Ph, Cy). Formation of the first allenyl carbene complexes;Journal of Organometallic Chemistry;2001-12
5. Structure and reactivity of δ4-cyclobutadiene and cisoid-δ4(5e)-butadienyl-substituted rhenium complexes formed by reaction of [ReBr2{δ2(4e)-alkyne}(δ-C5H5)] with alkynes or o-diphenylphosphinostyrene *;Journal of the Chemical Society, Dalton Transactions;1997
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