A metal–organic framework functionalized with piperazine exhibiting enhanced CH4 storage

Author:

Zhang Mingxing12345,Chen Cong56789,Wang Qian56789,Fu Wensheng1234,Huang Kunlin1234,Zhou Wei10111213

Affiliation:

1. Department of Chemistry

2. Chongqing Normal University

3. Chongqing

4. China

5. State Key Laboratory of Coordination Chemistry

6. Collaborative Innovation Center of Advanced Microstructures

7. School of Chemistry and Chemical Engineering

8. Nanjing University

9. Nanjing 210093

10. NIST Center for Neutron Research

11. National Institute of Standards and Technology

12. Gaithersburg

13. USA

Abstract

NJU-Bai 19, the first cycloaliphatic ring (piperazine) functionalized MOF-505 analogue, exhibits a notably high methane storage capacity of 246 cm3 (STP) cm−3 (at room temperature and 65 bar) and a working capacity of 185 cm3 (STP) cm−3.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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4. The role of metal–organic frameworks in a carbon-neutral energy cycle

5. The Chemistry and Applications of Metal-Organic Frameworks

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