Photoelectrocatalytic H2 evolution from integrated photocatalysts adsorbed on NiO

Author:

Põldme Nils1234,O'Reilly Laura5678,Fletcher Ian9234,Portoles Jose9234,Sazanovich Igor V.101112134,Towrie Michael101112134,Long Conor5678,Vos Johannes G.5678,Pryce Mary T.5678,Gibson Elizabeth A.1234ORCID

Affiliation:

1. School of Natural and Environmental Science

2. Newcastle University

3. Newcastle upon Tyne

4. UK

5. School of Chemical Sciences

6. Dublin City University

7. Dublin 9

8. Ireland

9. NEXUS XPS Laboratory

10. Central Laser Facility

11. Research Complex at Harwell

12. STFC Rutherford Appleton Laboratory

13. Didcot

Abstract

A new approach to increasing the faradaic efficiency of dye-sensitised photocathodes for H2 evolution from water is described, using integrated photocatalysts based on a ruthenium 4,4′-diethoxycarboxy-2,2′-bipyridine chromophore linked via terpyridine or triazole to a Pd or Pt-based H+ reduction catalyst.

Funder

Engineering and Physical Sciences Research Council

Leverhulme Trust

Science and Technology Facilities Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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