Synthesis, structure and characterization of Cd2TeO3Cl2 with unprecedented [Cd2O6Cl4] octahedral dimers-Reference-Cited by-同舟云学术

Synthesis, structure and characterization of Cd₂TeO₃Cl₂ with unprecedented [Cd₂O₆Cl₄] octahedral dimers

Published:2023 Issue:44 Volume:52 Page:16297-16302
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Wang Linan¹²,Bai Chen¹,Kong Yingying¹,Iqbal Maqsood¹²,Chu Yu¹²^ORCID,Li Junjie¹²^ORCID

Affiliation:

1. Research Center for Crystal Materials; CAS Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry, CAS, Urumqi 830011, China

2. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

A new mixed anionic compound Cd2TeO3Cl2 has been synthesized with CdCl2 as flux, which shows a mixed cationic layer structure constituted by distorted [TeO3], mixed anionic [Cd2O6Cl4] chains, and unprecedented [Cd2O6Cl4] octahedral dimers.

Funder

National Natural Science Foundation of China

Xinjiang Key Laboratory of Electronic Information Materials and Devices

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT02515B

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