Terminal alkyne insertion into a thiolate-bridged dirhodium hydride complex derived from heterolytic cleavage of H2-Reference-Cited by-同舟云学术

Terminal alkyne insertion into a thiolate-bridged dirhodium hydride complex derived from heterolytic cleavage of H2

Published:2018 Issue:79 Volume:54 Page:11112-11115
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Zhao Xiangyu¹²³⁴,Yang Dawei¹²³⁴^ORCID,Zhang Yahui¹²³⁴,Wang Baomin¹²³⁴^ORCID,Qu Jingping¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Fine Chemicals

2. Dalian University of Technology

3. Dalian 116024

4. P. R. China

5. Key Laboratory for Advanced Materials

Abstract

A thiolate-bridged dirhodium complex facilitates H₂ heterolysis to generate hydride species, then terminal alkyne insertion affords σ:π alkenyl bridged complexes.

Funder

National Natural Science Foundation of China

Ministry of Education of the People's Republic of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC05738A

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