Bis(neopentylglycolato)diboron (B2nep2) as a bidentate ligand and a reducing agent for early transition metal chlorides giving MCl4(B2nep2) complexes-Reference-Cited by-同舟云学术

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Bis(neopentylglycolato)diboron (B₂nep₂) as a bidentate ligand and a reducing agent for early transition metal chlorides giving MCl₄(B₂nep₂) complexes

Published:2023 Issue:37 Volume:52 Page:13154-13160
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Hosoya Hiromu¹,Akiyama Takuya¹,Mashima Kazushi²,Tsurugi Hayato¹^ORCID

Affiliation:

1. Department of Chemistry, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan

2. Graduate School of Pharmaceutical Sciences, Osaka University, Suita, Osaka 565-0871, Japan

Abstract

We found that bis(neopentylglycolato)diboron (B2nep2) served as a bidentate ligand and a one-electron reducing agent for early transition metal chlorides to afford MCl4(B2nep2).

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT01828H

Reference55 articles.

1. Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse

2. Transition-metal-free B–B and B–interelement reactions with organic molecules

3. Theoretical study on homolytic B–B cleavages of diboron(4) compounds

4. Formation and Reactivity of Electron-Precise B−B Single and Multiple Bonds

5. New avenues for C–B bond formation via radical intermediates

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