Zirconium and hafnium polyhedral oligosilsesquioxane complexes – green homogeneous catalysts in the formation of bio-derived ethers via a MPV/etherification reaction cascade
Author:
Affiliation:
1. Department of Chemistry and Biochemistry
2. Texas Tech University
3. Lubbock
4. USA
Abstract
Newly designed POSS supported zirconium and hafnium isopropoxides are robust, durable and selective homogeneous catalysts for the conversion of hydroxymethylfurfural to bis(isopropoxymethyl)furane via MPV/etherification reaction with isopropanol as a green solvent/reagent.
Funder
U.S. Department of Energy
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2021/CY/D0CY01864C
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