Probe metal binding mode of imine covalent organic frameworks: cycloiridation for (photo)catalytic hydrogen evolution from formate-Reference-Cited by-同舟云学术

Probe metal binding mode of imine covalent organic frameworks: cycloiridation for (photo)catalytic hydrogen evolution from formate

Published:2021 Issue: Volume: Page:
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Hu Jiyun¹²³⁴^ORCID,Mehrabi Hamed⁵²³⁴^ORCID,Meng Yin-Shan⁶⁷⁸⁹^ORCID,Taylor Maddison¹²³⁴,Zhan Jin-Hui¹⁰¹¹¹²¹³⁹,Yan Qigeng¹⁴²³⁴,Benamara Mourad¹⁴²³⁴,Coridan Robert H.¹²³⁴^ORCID,Beyzavi Hudson¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. University of Arkansas

3. Fayetteville

4. USA

5. Material Science and Engineering Program

6. State Key Laboratory of Fine Chemicals

7. Dalian University of Technology

8. Dalian

9. China

10. State Key Laboratory of Multiphase Complex System

11. Institute of Process Engineering

12. Chinese Academy of Sciences

13. Beijing

14. Institute for Nanoscience & Engineering

Abstract

This study describes cyclometallation as a new metal binding mode for imine-based COFs. The iridacycle decorated COF could be used for catalytic hydrogen evolution from aqueous formate solution with high stability and high efficacy.

Funder

University of Arkansas

National Natural Science Foundation of China

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC01692J

Reference73 articles.

1. Covalent Organic Frameworks: Structures, Synthesis, and Applications