Magnesium–halobenzene bonding: mapping the halogen sigma-hole with a Lewis-acidic complex-Reference-Cited by-同舟云学术

Magnesium–halobenzene bonding: mapping the halogen sigma-hole with a Lewis-acidic complex

Published:2021 Issue:7 Volume:12 Page:2410-2418
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Friedrich Alexander¹²³⁴,Pahl Jürgen¹²³⁴,Eyselein Jonathan¹²³⁴,Langer Jens¹²³⁴^ORCID,van Eikema Hommes Nico⁵²⁶⁴⁷^ORCID,Görling Andreas⁷²³⁴,Harder Sjoerd¹²³⁴^ORCID

Affiliation:

1. Inorganic and Organometallic Chemistry

2. Friedrich-Alexander-Universität Erlangen-Nürnberg

3. 91058 Erlangen

4. Germany

5. Computer Chemistry Center

6. 91052 Erlangen

7. Theoretical Chemistry

Abstract

Complexes of a highly Lewis acidic Mg cation and the full series of Ph–X (X = F, Cl, Br, I) have been structurally characterized. The Mg⋯X–Ph angle decreases with halogen size on account of the growing halogen σ-hole.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC06321E

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