Channel-wall functionalization in covalent organic frameworks for the enhancement of CO2 uptake and CO2/N2 selectivity
Author:
Affiliation:
1. Department of Chemistry
2. Dalian University of Technology
3. Dalian 116024
4. China
5. Dalian Institute of Chemical Physics
6. Chinese Academy of Sciences
7. Dalian 116023
8. State Key Laboratory of Fine Chemicals
Abstract
Two structurally similar groups with one being CO2-philic but the other not were anchored into the channel walls of 2D COFs. The decreased surface area of COFs undoubtedly decreased CO2 adsorption if too many functional groups were introduced.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA04859E
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